Hi Ray, sorry I didn't reply to this sooner, but my lifes been totally manic these past couple of months & not had time to come on here very much.
Ok, reds can be a right pain in the butt, but even so, you shouldn't be experiencing the problems that you are. Reds by their very nature change colour as they darken..Period. You can also get what's known as "metamerism" with reds. The different manufacturers, use different pigments to make their own formulations to obtain a specific colour. In the manufacture process, these pigments have differing "strengths" of colour between the different manufacturers. Confused yet lol, ok have you ever seen a red car that looks to be one solid red?? Have you then seen that car under sodium street lights & you can see a difference in shade between some panels, normally looking more orange in colour?? this is metamerism, whereby the sodium lights can show that a different manufacturers paint has been applied, to that of the original (by "picking out" the different strength pigment in the mixing process).
So what has this got to do with you, you may well ask?? Well, as reds are curing the surface hardens & in doing so the pigments on the surface start to darken. Eventually, as the paint through hardens the red will become a solid colour, ie the same shade throughout its thickness. To be honest, if you stayed in there painting all day, I wouldn't have expected this sort of thing to happen. As has been said, it looks as if the surface of one layer of paint has hardened & cured fully, before the subsequent layers have "through dried".
Now I know that this paint has been on the car for some time now, so this really shouldn't be a problem. My car has between 6 & 8 coats on it, all sprayed over the period of about 6 hours & this problem didn't occur. I've never known it to happen between coats like this, it looks to me like metamerism, whereby a different paint or a different batch of the same paint has been used.
Did you use the same paint as was first put on the rest of the car?? The reason I ask is because you've not had a problem with the rest of the car have you?? Is the roof now painted with a different/new paint as opposed to the one used on the rest of the car? Did you use any of the older paint first to build up the colour & then coat over that with a new tin of paint??
If the answer to all of the above is no, then you've a problem with "pigment seperation". I've had a similar situation whereby I painted a car & when I came to flat & buff it, it came out all blotchy as soon as the fully cured surface had been broken through. That was down to there not being any "binders" added to the paint by the paint factors, but it gives the same result as you're experiencing. The reason I say "fully cured surface" is because paint, even when baked, fully cures surface first & then "through hardens afterwards" Unfortunately, people think that when a car has been baked, it's hard all the way through to the primer substrates, this is not the case. So, when you have an air dry situation like yours, the surface may be hard but the subsequent layers underneath are definately not as hard.
Pigment seperation can occur if the paint is over thinned when being sprayed on heavy. The pigments of the paint are able to "float" to the surface of the colour/paint & dry very quickly. Now you can maybe see where I was coming from ealier in this thread re metamerism. The pigments that "float" to the surface when over thinned, dry quickly & in doing so will be darker than the paint underneath it. Unfortunately, if this is the case, then even when the paint beneath the over thinned layer fully cures, it will not be as dark as the overthinned layer as the pigments have metamerised. The only cure is to repaint it I'm afraid.
As to painting over 1500 grit, I'd be inclined to hit it with some 600 or 800 as the 1500 won't give good mechanical grip to the new paint being applied. hth
cheers...Nige